Tom Brady won his first Super Bowl with the New England Patriots in the year 2002. The Patriots emerged victorious in Super Bowl XXXVI, which was held on February 3, 2002. In that game, the Patriots defeated the St. Louis Rams by a score of 20-17, and Tom Brady was named the game's Most Valuable Player (MVP). This victory marked the beginning of Brady's unprecedented success in the NFL, as he went on to win several more Super Bowls throughout his career.